The section of “Orbital Contribution: Effect of Ligand-Field” from the chapter entitled “Magnetic Properties of Transition Metal Complexes” covers the following topics:
- Ligand Field Effect on the Orbital Contribution in Octahedral Complexes: Electronic configurations with orbital magnet, Electronic configurations without orbital magnet.
- Ligand Field Effect on the Orbital Contribution in Tetrahedral Complexes: Electronic configurations with orbital magnet, Electronic configurations without orbital magnet.
- Effect of Spin-Orbital Coupling on the Orbital Contribution: Calculation of µeff for A1 terms, Calculation of µeff for E terms, Calculation of µeff for A2 terms.
- Temperature Independent Paramagnetism (TIP).
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